Barcelona takes on Olympiacos at the Estadi Olímpic Lluís Companys on Tuesday, Oct. 21. Kickoff is set for 6:45 p.m. CET local time in Spain, making it a 12:45 p.m. ET or 9:45 a.m. PT start in the US, a 5:45 p.m. BST kickoff in the UK, and a 3:45 a.m. AEDT start in Australia on Wednesday.

Elsewhere, Arsenal will look to extend their unbeaten September run into October with a matchup against Olympiakos. The Gunners won their first Champions League game against Athletic Bilbao and went 2-0-1 in Premier League play last month, while also advancing to the second round of the Carabao Cup.

Villarreal vs Man City is scheduled for an 8pm BST kick-off tonight, Tuesday October 21, 2025. The match will take place at the Estadio de la Ceramica. TV channel: In the UK, the game will be televised live on TNT Sports 1, with coverage starting at 7.45pm BST after Barcelona vs Olympiacos.

American soccer fans can stream this game along with every fixture of this season's tournament via Paramount Plus, which has exclusive live English-language broadcast rights in the US for the UEFA Champions League.

ANOTHER blockbuster night of Champions League action has concluded. Chelsea hammered Dutch giants Ajax, who went down to ten-men after an early red card, with Marc Guiu and Tyrqiue George among

Bayern Munich started their match against Club Brugge with a 17-year-old named Lennart Karl, a bold move from Vincent Kompany. Inside five minutes, said 17-year-old opens the scoring in an eventual 4-0 rout.